吕东灿,袁帅,赵仲麟,袁超,袁志华,马斌强,刘运权

• 1:河南农业大学理学院
• 2:四川农业大学机电学院
• 3:河南农业大学机电工程学院
• 4:厦门大学能源学院

摘要(Abstract)：

在温和条件下研究了氢碘酸还原生物质基多元醇制备液体燃料的过程,使用气相色谱质谱仪(GC-MS)和红外光谱仪(FT-IR)分析了产物组成。结果表明,山梨醇和甘露醇为原料制备的液体产物中主要成分是C_(12)H_(16)、C_(12)H_(18)、C_(12)H_(20)、C_(12)H_(22)和C_(18)H_(26)等烃类物质。通过与碱的醇溶液反应将副产物碘代烷转化为烃,经旋转蒸发和减压蒸馏获得纯净的高碳烃产品。山梨醇、甘露醇以及二者混合物制备出的高碳烃的产率分别是81.1%、73.2%和77.3%。本研究获得的高碳烃产品是一种有前景的液体燃料,其含水量为0.1%,密度为0.83~0.84 g·mL~(-1),含氧量为2.0%~2.2%,热值均高于42 MJ·kg~(-1)。

关键词(KeyWords)： 生物质;山梨醇;甘露醇;氢碘酸;高碳烃

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金项目(21276214)

作者(Author): 吕东灿,袁帅,赵仲麟,袁超,袁志华,马斌强,刘运权

DOI: 10.16445/j.cnki.1000-2340.2016.02.011

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