2007 03 No.141 356-362
木质素的测定方法研究进展
基金项目(Foundation):
国家烟草专卖局资助项目(110200302007)
邮箱(Email):
DOI:
10.16445/j.cnki.1000-2340.2007.03.026
中文作者单位:
河南农业大学,河南农业大学,河南农业大学,黄河中心医院药剂科,河南农业大学 河南郑州450002,河南郑州450002,河南郑州450002,河南郑州450003,河南郑州450002
摘要(Abstract):
对木质素的制备、总量的测定及其结构和分子量的测定等进行了综述,并分析了这些测定方法存在的问题,指出了将太赫兹技术应用于木质素测定的前景.
关键词(KeyWords):
木质素;;降解;;太赫兹
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参考文献
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[19]TAKAO K,YOSHIHIRO S.Delignification mechanismduring high-boiling Solvent pulping,part 4,effect of areducing sugar on the degradation of guaiacylglycerol-b-guaiacyl ethe[J].Journal of wood chemistry and tech-nology,2003,23(3/4):233-248.
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[21]程贤建,陈云平,吴耿云,等.高沸醇木质素的研究进展[J].化工进展,2006,25(2):147-151.
[22]BRINKMANN K,BLASCHKE L,POLLE A.Compari-son of different methods for lignin determination as abasis for calibration of near-infrared reflectance spec-troscopy and implications of lignoproteins[J].Journalof Chemical Ecology,2002,28(12):2483-2501.
[23]ALVES A,SCHWANNINGER M,PEREIRA H,et al.Calibration of NIR to assess lignin composition(H/Gratio)in maritime pine wood using analytical pyrolysisas the reference method[J].Holzforschung,2006,60(1):29-31.
[24]霍夫里特M,斯泰比歇尔A.生物高分子[M].第1卷.郭圣荣,译.北京:化学工业出版社,2004:99-128.
[25]DENCE C W.The determination of lignin[M]//LIN SY,DENCE C W.Methods in lignin chemistry.Berlin:Spinger-Verlag,1992,33-61.
[26]GOERING H K,VAN SOEST P J.Forage fiber analy-ses(apparatus,reagents,procedures and some appli-cations)[J].Agr Handbk,1970,3:379.
[27]HSTFIELD R D,JUNG H J G,RALPH J,et al.Acomparison of the insoluble residues produced by theklason ligning and acid detergent lignin procedures[J].J Sci Food Agric,1994,65:51-58.
[28]KONDO T,MIZUNO K,KATO T.Variation in solubil-ity of lignin in acid determination and in alkali[J].JJapan Grass Sci,1987,33:296-299.
[29]LOWEY J B,CONLAN L L,SCHLINK A C,et al.Acid detergent dispersible lignin in tropical grasses[J].J Sci Food Agri,1994,65:41-49.
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[31]BRUCE R J,WEST C A.Elicitation of lignin biosyn-thesis and isoperoxdidase activity by petic fragments insuspension cultures of castor bean[J].Plant Phys,1989,91:889-897.
[32]BONELLO P,HELLER W,SANDERMANN H.Ozoneeffects on root-disease susceptibility and defenses re-sponse in mycorrhizal and non-mycorrhizal seedings ofScots pine(Pinus sylvestrisL.)[J].New phytol,1993,124:653-663.
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[34]HATFIELD R,FUKUSHIMA R S.Can lignin beaccurately measured?[J]Crop Science,2005,45(3):832-839.
[35]RODRIGUES J,FAIX O,PEREIRA H.Improvementof the acetylbromide method for lignin determinationwithin large scale screening programs[J].Holz Als Ro-hund Werkstoff,1999,57(5):341-345.
[36]VANZYI J D.Notes on the spctrophotometric determi-nation of lignin in wood samples[J].Wood Sci Tech,1978,12:251-259.
[37]IIYAMA K,WALLIS A.An improved acetyl bromideprocedure for determining lignin in woods and woodpulps[J].Wood Sci Technol,1988,22:271-280.
[38]HATFIELD R D,GRABER J,RALPH J,et al.Usingthe acetyl bromide assay to determine lignin concentra-tions in herbaceous plants:some cautionary notes[J].J Agric Food Chem,1999,47:628-632.
[39]FUKUSHIMA R S,HATFIELD R D.Extraction and i-solation of lignin for utilization as a standard to deter-mine lignin concentration using the acetyl bromide spec-trophotometric method[J].J Agric Food Chem,2001,49:3133-3139.
[40]SARKANEN K V,ISLAM A,ERSON C D.Ozonation[M]//LINS Y,AND DENCE C W.Methods in ligninchemistry.Berlin:Springver-verlag.1992:387-406.
[41]BOSE S K,WILSON K L,FRANCIS,et al.Lignin a-nalysis by permanganate oxidation.1.Native sprucelignin[J].Holzforschung,1998,52:297-303.
[42]SCHULTZ T P,TEMPLETON M C,MCGINNS G D.Rapid determination of lignocelluose by diffuse reflec-tance FT-IR[J].Anal Chem,1985,57:2867-2869.
[43]MCLELLANTM,ABER J D,MARTINME.Determi-nation of nitrogen lignin,and cellulose contents of de-composing leaf material by NIRS[J].Can J ForestRes,1991,21:1684-1688.
[44]JOFFRE R,GILLON D,DARDENCE P,et al.Theuse of NIRS in litter decomposition studies[J].AnnSci forest,1992,49:481-488.
[45]GILLON D,TOFFRE R,IBRAHIMA A.Can litter de-composability be predicted by NIRS[J].Can J forestRes,1993,23:2552-2559.
[45]BOLSTER K L,MARTINME,ABER J D.Decrimina-tion of carbon fraction and nitrogen concentration in treefoliage by NIRS:a comparison of statistical method[J].Can J forest Resh,1996,26:590-600.
[46]AMARI M.Application of NIRS to forge analysis andpredication of TDN contents[J].Japan Agri Research,1997,31(1):55-63.
[47]MAGIL A H,ABER J D.Long-term effects of experi-mental nitrogen additions on foliar litter decay and hu-mus formation in forest ecosystems[J].Plant Soil,1998,203:101-112.
[48]ABER J D,BOLSTER K L,NEWMANS D,et al.An-alyses of forest foliage.II.Measurement of carbon frac-tion and nitrogen content by end member analysis[J].J NIRS,1994,2:15-23.
[49]NEWMANS D,SONLIAME,ABER J D,et al.Anal-ysis of forest foliage.I.Laboratory procedures for prox-imate carbon fractionation and nitrogen determination[J].J NIRS,1994,2:5-14.
[50]HARMON M E,LAJTHA K.Analysis of detritus andorganic horizons for mineral and organic constituents[M]//ROERSTON G P,COLEMAN D C,BLEDSOEC S,et al.Standard soil methods for long-term ecologi-cal research.New York:Oxford University press,1999:146-165.
[51]ONO K,HIRAIDE M,AMARI M,Determination oflignin,holocellulose,and organic solvent extractives infresh leaf,litter fall,and organic material on forestfloor using NIRS[J].Journal of Forest Research,2003,8(3):191-198.
[52]AGARWAL UP,ATALLAR H.FT-Raman spectrosco-py:what it is and what it can do for lignocellosic re-search[C]//Proceedings 8th symp Wood and pulp.Chem Helsinki,1995:67.
[53]AGARWAL U P,WEINSTOCK I A,ATALLA R H,FT-Raman spectroscopy:A rapid non-invasive tech-nique for direct measurement of lignin in kraft pulps,proceedings 1996 inter[M].Atlanta:TAPPI Press,1996:531.
[54]AGARWAL U P,MCSWEENY J.Photoyellowing ofthermomechanical pulps:Loooking beyond a-carbonyland ethylenic groups as the initiating structures[J].Wood Chemistry Tech,1997,17:1-26.
[55]LUNDQUISTK.Proton HNMR studies of lignin[M]//LIN S Y,DENCE C W.Methods in lignin chemistry.Berlin:Springer-Verlag,1992:242-249.
[56]周学飞,余家銮,陈嘉翔.核磁共振法在研究木素和碳水化合物结构方面的应用[J].中国造纸学报,1998,13(1):86-91.
[57]ARCHIPOV Y,ARGYROPOULOS D S,BOLKER H,etal.31P-NMR spectroscopy in wood chemistry[J].Phosphite Derivatives of Carbohydrates,1991,220:49-61.
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基本信息:
DOI：10.16445/j.cnki.1000-2340.2007.03.026
中图分类号:Q946
引用信息:
[1]苏同福,高玉珍,刘霞等.木质素的测定方法研究进展[J].河南农业大学学报,2007,No.141(03):356-362.DOI:10.16445/j.cnki.1000-2340.2007.03.026.
基金信息:
国家烟草专卖局资助项目(110200302007)
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